Purposive Design of Stretchable Composite Electrodes for Strain‐Negative, Strain‐Neutral, and Strain‐Positive Ionic Sensors

Abstract Soft ionic sensors have emerged as a promising device form to accommodate various future electronic applications. One of the hurdles in ionic sensors is that the sensing signals by mechanical deformation and other stimuli are mixed up. Although the performance of the ionic sensors is highly dependent on the structure of electrodes, systematic investigation of purposive electrode design has been rarely explored. This study proposes a simple strategy for designing stretchable composite electrodes which make the ionic sensor strain‐negative, strain‐neutral, and strain‐positive. This study reveals that such strain‐responses can be obtained by adjusting the surface coverage of the electrically‐effective conductive fillers. On the basis of the concept, deposition of a Au film on an elastomer composite and crack formation of the Au film are presented for the practical fabrication of a highly reproducible strain‐neutral ionic sensor. A completely strain‐independent temperature sensor is demonstrated by using the Au crack‐based ionic sensor. In addition, this study demonstrates a two‐terminal shear sensor capable of recognizing shear directions by combining the strain‐positive and strain‐negative electrodes.