水热碳化
热液循环
碳化
煤
化学工程
材料科学
制浆造纸工业
水热合成
废物管理
复合材料
扫描电子显微镜
工程类
作者
Zhixiang Xu,Xue-Qin Ma,Yaqi Shan,Xun Hu,Sameh M. Osman,Junjie Liao,Pei-Gao Duan,Rafael Luque
出处
期刊:ACS Sustainable Chemistry & Engineering
[American Chemical Society]
日期:2022-02-28
卷期号:10 (10): 3335-3345
被引量:11
标识
DOI:10.1021/acssuschemeng.1c08338
摘要
A new concept is proposed for the production of artificial coal under HTC conditions using Mg(NO3)2 as an oxidant in a short time, which is found to enhance the coalification degree of hydrochar from lignocellulosic materials. Pressure promotes decarboxylation reactions of lignocellulose to form hollow smooth-faced regular spherical particles, avoiding the agglomeration of hydrochar particles. In parallel, oxidation can break down the biopolymer structure to form low-molecular-weight compounds, which is found to be a key step during artificial coal formation. The artificial coal synthesized has a high degree of coalification.
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