解聚
化学
木质素
水溶液
氢氧化钠
单体
溶剂
有机化学
氧化剂
深共晶溶剂
绿色化学
聚合物
催化作用
反应机理
共晶体系
合金
作者
Victor Zhenquan Ong,Khai Jie Yong,Ta Yeong Wu
标识
DOI:10.1016/j.indcrop.2022.115911
摘要
Lignin is a promising sustainable feedstock for the production of renewable aromatic chemicals. However, conventional depolymerization techniques often require high pressure and temperature. This study aimed to address this limitation by investigating the application of a combined solvent containing aqueous deep eutectic solvent and sodium hydroxide in the depolymerization of Kraft lignin at atmospheric pressure. The effects of temperature, duration, and NaOH concentration were investigated. Under the depolymerization conditions of 150 °C, 20 min, 7.5% (w/v) NaOH, an aromatic monomer yield of 23.06 mg/g was achieved. Various metal chloride catalysts, including LiCl, CuCl2, and FeCl3, were added as oxidizing agents to promote lignin depolymerization. The synergistic effects of the combined solvent with CuCl2 resulted in an aromatic monomer yield of 69.75 mg/g. Physical and chemical characterization of lignin samples was performed to provide further evidence to support the effectiveness of the depolymerization process proposed in this study. The use of NaOH-aqueous DES as a depolymerization medium could be a promising method for promoting a milder and inherently safer depolymerization system.
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