双金属片
4-硝基苯酚
催化作用
材料科学
双金属
复合数
纳米颗粒
选择性催化还原
化学工程
过渡金属
协同催化
硝基苯酚
电子转移
金属
纳米技术
冶金
光化学
复合材料
化学
有机化学
工程类
作者
Peicheng Jiang,Wei Guo,Peng Jin,Wei Peng,Huiyong Li,Chang Peng,Shu Chen
标识
DOI:10.1016/j.matlet.2023.134918
摘要
Catalytic reduction has been considered as one of effective methods for the conversion of organic pollutants. However, a lack of efficient catalyst precludes its practical application. Herein, a novel transition metal carbides-supported bimetallic Ag/Cu nanoparticles composite (Ag/Cu/MXene) catalyst was prepared by one-pot reduction method. The MXene as a carrier medium effectively promoted the riping and immobilization of bimetallic Ag/Cu nanoparticles. The synergistic effects of the composite catalyst improved electron transfer capacity, resulting in high catalytic activity for the reduction of 4-nitrophenol (4-NP). The turnover frequency (TOF) was high up to 1127.2 h−1, which was higher than that of MXene-supported monometallic Ag or Cu catalyst. In addition, the conversion efficiency for 4-NP reduction by Ag/Cu/MXene was high up to 90% after five recycles. Our findings presented here are not only potential for catalytic applications, but also provide a foundation for the development of efficient MXene-based catalysts.
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