热电效应
质子
能量转换
储能
电子转移
离子键合
塞贝克系数
氧化还原
对苯二酚
材料科学
化学
光电子学
化学物理
功率(物理)
离子
热力学
无机化学
物理化学
物理
量子力学
有机化学
作者
Yang Wang,Yongqiang Dai,Longbin Li,Lin Yu,Wei Xue
标识
DOI:10.1002/anie.202307947
摘要
Low-grade heat is ubiquitous in the environment and its thermoelectric conversion by the ionic conductors remains a challenge because of the low efficiency and poor sustainability. Here we demonstrate that the thermoelectric performances can be boosted by combining the Soret effect of protons and proton-coupled electron transfer (PCET) reaction of benzoquinone and hydroquinone in hydrogels. An overall enhancement of thermopower (25.9 mV K-1 ), power factor (5 mW m-1 K-2 ), figure of merit (>2.4) and continuity of power output is achieved. Moreover, an energy-storage function can be achieved by the redox couple, and a retained power output of 27.7 %, or 14 mW m-2 for more than 3 hours is obtained by the re-balance of PCET reactants in the hydrogel after the removal of the temperature gradient.
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