Critical Threshold for Bubble-like Nucleation during Pseudoboiling at Supercritical Pressures

Supercritical pseudoboiling was proposed in the 1950s-1960s. Recently, evaporation-like and boiling-like heat transfer have been directly observed in macroscopic scales, and the contribution of pseudoboiling to the total heat transfer rate has been quantitatively characterized experimentally. Here, we explore the critical threshold to generate a bubble-like nucleus at supercritical pressure at the atomic scale, characterized by the total energy (Te = Ke + Pe, where Ke and Pe are kinetic energy and potential energy, respectively). Molecular dynamics simulations are performed, including an argon fluid box heated by a solid wall having its temperature above the fluid temperature. The fluid pressure is controlled by a movable piston wall opposite the heating wall. The effects of pressure, nonuniform heating, and surface wettability on pseudoboiling are investigated. It is found that the criterion Te > 0 should be satisfied for subcritical boiling, matching that reported previously. The criterion for supercritical pseudoboiling was newly obtained such that Te > 0.012 eV at 8 MPa for argon, but the threshold increases as pressure increases. Nonuniform heating and surface wettability do not affect the critical threshold of Te for bubble-like nucleation but affect the location of the initially generated bubble-like nucleus and the stabilized pseudofilm or pseudonucleate heat transfer modes, where the former is similar to (vapor) film boiling and the latter is similar to nucleate boiling at subcritical pressure. Because pseudoboiling occurs without surface tension at supercritical pressure, we observe that the bubble-like structure may not display a perfectly smooth gas-liquid interface but may display an irregular pattern instead. Our work explains pseudoboiling from the viewpoint of the competition between kinetic energy and potential energy and presents a link regarding boiling in the two domains of subcritical pressure and supercritical pressure.