居里温度
材料科学
陶瓷
电阻率和电导率
退火(玻璃)
粒度
兴奋剂
分析化学(期刊)
氧气
压电
热稳定性
离子
矿物学
晶粒生长
冶金
化学工程
凝聚态物理
复合材料
化学
光电子学
物理
工程类
有机化学
色谱法
铁磁性
量子力学
作者
Xinji Yang,Ning Chen,Fei Wang,Manjing Tang,Jie Xing,Jianguo Zhu
摘要
Abstract As a typical perovskite‐like layered structure (PLS) ceramic, Sr 2 Nb 2 O 7 (SNO) possesses a high Curie temperature T C value above 1300°C, which is expected to work in higher temperature environment. However, pure SNO presents a piezoelectric constant d 33 value of ∼ 1 pC/N. Hence, (Li, Ce) ions are doped in SNO ceramics, which increases the distortion of oxygen octahedrons and enhances the intrinsic contribution of piezoelectric properties. The increased domain size with large proportion of high response areas means that the extrinsic contribution is also improved. The introduction of (Li, Ce) ions can also promote ceramic's grain growth and reduce oxygen vacancies, leading to the improvement of electrical properties. The optimal component Sr 1.96 (Li, Ce) 0.02 Nb 2 O 7 ceramics exhibit a d 33 value of 3.1 pC/N, a higher resistivity of 1.65×10 6 Ω·cm at 700°C and an excellent thermal stability (a d 33 value of 3.0 pC/N after annealing at 1200°C for 2 h). This work provides an effective approach with simple process and low cost for the application of PLS materials in high‐temperature environments.
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