Femtosecond Electron Diffraction Reveals Local Disorder and Local Anharmonicity in Thermoelectric SnSe

Abstract In addition to long‐range periodicity, local disorder, with local structures deviating from the average lattice structure, dominates the physical properties of phonons, electrons and spin subsystems in crystalline functional materials. Experimentally characterizing the 3D atomic configuration of such a local disorder and correlating it with advanced functions remains challenging. Using a combination of femtosecond electron diffraction, structure factor calculations and TDDFT‐MD simulations, we exclusively identified the static local disorder and its local anharmonicity in thermoelectric SnSe. The ultrafast structural dynamics reveal that the crystalline SnSe is composed of multiple locally correlated configurations dominated by the static off‐symmetry displacements of Sn (∼0.4 Å) and such a set of locally correlated structures is termed local disorder. Moreover, the anharmonicity of this local disorder induces an ultrafast atomic displacement within 100 fs, indicating the signature of probable THz Einstein oscillators. The identified local disorder and local anharmonicity suggest a glass‐like thermal transport channel, which updates the fundamental insight into the long‐debated ultralow thermal conductivity of SnSe. Our method of revealing the 3D local disorder and the locally correlated interactions by ultrafast structural dynamics will inspire broad interest in the construction of structure‐property relationships in material science. This article is protected by copyright. All rights reserved