Surface modification of commercial carbon black by silane coupling agents for improving dispersibility in rubber compounds

炭黑 表面改性 天然橡胶 材料科学 硅烷 色散(光学) 拉曼光谱 填料(材料) 碳纤维 化学工程 嫁接 傅里叶变换红外光谱 复合材料 高分子化学 聚合物 复合数 物理 光学 工程类
作者
Farzaneh Jaberi Mofrad,Saeed Ostad Movahed,Ali Ahmadpour
出处
期刊:Journal of Applied Polymer Science [Wiley]
卷期号:141 (13) 被引量:3
标识
DOI:10.1002/app.55155
摘要

Abstract The dispersion of a filler in a rubber matrix is a crucial parameter affecting the mechanical and dynamical properties of a rubber compound. It is the current issue of the rubber compounding industry because, most fillers are categorized as a mineral, while the rubber is an organic material. The surface modification of the filler has been accepted as an effective technique for the improvement of the abovementioned parameter. First, the surface premodification of commercial carbon black with a grade of N660 (CB) was implemented by four different oxidation methods. After that, among of used methods, the oxidation method using citric acid was selected to produce modified carbon black (CB‐Oxi) for further treatment. Subsequently, the coupling agent, Bis[3‐(triethoxysilyl)propyl] tetrasulfide (TESPT) was functionalized on the surface of CB‐Oxi to produce modified‐CB‐Oxi. Also, for comparison purposes, the TESPT functionalization was accomplished on untreated CB to form modified‐CB. The FTIR spectra of CB‐Oxi showed using the premodification method introduced the hydroxyl and carboxyl groups on the surface of CB. The correspondent spectra for modified‐CB‐Oxi confirmed the existence of silane groups on the surface of the carbon black. However, the mentioned silane groups were not observed on the surface of modified‐CB. The findings were strengthened by several characteristic techniques including, FESEM, XRD, EDS, CHNS elemental analysis, and RAMAN spectra. The FESEM graphs and elemental mapping showed homogeneous dispersion and uniform distribution of sulfur and silicon elements on the modified‐CB‐Oxi surface. According to RAMAN spectra, the disturbance in the structure of carbon black graphite was reduced after surface modification. modified‐CB‐Oxi is proposed as a potential substitute filler for current commercial carbon black in rubber compounding.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
刚刚
zxx发布了新的文献求助10
1秒前
2秒前
直率小霜完成签到,获得积分10
3秒前
薰硝壤应助蜂蜜柚子采纳,获得50
3秒前
1084497228完成签到 ,获得积分10
4秒前
ymh完成签到,获得积分10
5秒前
Elian发布了新的文献求助10
5秒前
CreyCat发布了新的文献求助10
5秒前
6秒前
复杂的青发布了新的文献求助10
6秒前
azhu完成签到,获得积分10
6秒前
6秒前
7秒前
Heima发布了新的文献求助10
7秒前
张三坟应助xiahou采纳,获得30
8秒前
薰硝壤应助lumen采纳,获得30
8秒前
所所应助xin采纳,获得10
9秒前
cannon8应助木子采纳,获得20
9秒前
忘川完成签到,获得积分10
11秒前
热心市民小红花应助tzy采纳,获得10
12秒前
顾矜应助lin采纳,获得10
12秒前
心随以动发布了新的文献求助10
12秒前
zxy发布了新的文献求助10
12秒前
深情安青应助哈比采纳,获得10
14秒前
15秒前
怕孤独的鹭洋完成签到,获得积分10
16秒前
黄花菜发布了新的文献求助10
17秒前
Yuna完成签到,获得积分10
17秒前
wangdada发布了新的文献求助30
17秒前
klbzw03完成签到,获得积分10
18秒前
千千的君子兰完成签到,获得积分10
19秒前
19秒前
Heima完成签到,获得积分20
19秒前
68发布了新的文献求助10
20秒前
20秒前
21秒前
oyyh完成签到,获得积分20
21秒前
我瞎蒙发布了新的文献求助10
21秒前
科研菜鸟完成签到,获得积分20
23秒前
高分求助中
Sustainability in Tides Chemistry 2000
The ACS Guide to Scholarly Communication 2000
Studien zur Ideengeschichte der Gesetzgebung 1000
TM 5-855-1(Fundamentals of protective design for conventional weapons) 1000
Pharmacogenomics: Applications to Patient Care, Third Edition 800
Ожившие листья и блуждающие цветы. Практическое руководство по содержанию богомолов [Alive leaves and wandering flowers. A practical guide for keeping praying mantises] 500
A Dissection Guide & Atlas to the Rabbit 500
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3079267
求助须知:如何正确求助?哪些是违规求助? 2731896
关于积分的说明 7521337
捐赠科研通 2380638
什么是DOI,文献DOI怎么找? 1262413
科研通“疑难数据库(出版商)”最低求助积分说明 611928
版权声明 597414