Magnetic Fe3O4 /Al2O3 /MnO2 ternary nanocomposite: Synthesis and characterization for phosphorus desorption from acidic soils using dialysis membrane tube

Abstract

Monitoring phosphorus fertilization is crucial for controlling the concentration of biologically available soil P. Over the years, several methodologies have been used, including successive cropping in a greenhouse or field, as well as extractions employing P sink procedures. The latter procedures are ideal laboratory experiments to show the soil's ability to supply P and to explore the P-residual release kinetics. Following these methodologies, long-term P desorption studies have been developed using dialysis membrane tubes filled with nanomaterial solutions. In this study, a magnetic nanocomposite (Fe₃O₄/Al₂O₃/MnO₂) was synthesized and characterized utilizing cutting-edge instruments such as XRD, FTIR, FAAS, BET, SEM, and EDX. The resulting material had a crystalline size and surface area of 22.75 nm and 203.69 m²/g, respectively, and was employed for long-term P-desorption and kinetics experiments while filled in dialysis membrane tubes. The P-desorption experiment was conducted on four separate acidic soil samples that were cultured for 122 days with four different P concentrations. The findings demonstrated a direct relationship between P-desorbed and P-treatment, as well as with desorption time. The minimum desorption was obtained from the control of Boji Dirmaji soil P0 (1.16–9.36) and the highest desorption from Nedjo soil with P3 (5.23–30.35 mg/kg) treatment over 1–28 days. The rate of P release from soil to solution or diffusion through the membrane was determined by pseudo-first-order kinetics with a rate constant (0.021–0.028 hr⁻¹). This method has the potential to measure fixed-P availability by mimicking it as a plant would, with high P-desorption efficiency and quick P-release capacity.