Recent Progress on Copper‐Based Bimetallic Heterojunction Catalysts for CO2 Electrocatalysis: Unlocking the Mystery of Product Selectivity

Abstract Copper‐based bimetallic heterojunction catalysts facilitate the deep electrochemical reduction of CO 2 (eCO 2 RR) to produce high‐value‐added organic compounds, which hold significant promise. Understanding the influence of copper interactions with other metals on the adsorption strength of various intermediates is crucial as it directly impacts the reaction selectivity. In this review, an overview of the formation mechanism of various catalytic products in eCO 2 RR is provided and highlight the uniqueness of copper‐based catalysts. By considering the different metals' adsorption tendencies toward various reaction intermediates, metals are classified, including copper, into four categories. The significance and advantages of constructing bimetallic heterojunction catalysts are then discussed and delve into the research findings and current development status of different types of copper‐based bimetallic heterojunction catalysts. Finally, insights are offered into the design strategies for future high‐performance electrocatalysts, aiming to contribute to the development of eCO 2 RR to multi‐carbon fuels with high selectivity.