Efficient Catalytic Combustion of Cyclohexane over PdAg/Fe2O3 Catalysts under Low-Temperature Conditions: Establishing the Degradation Mechanism Using PTR-TOF-MS and in Situ DRIFTS

Cyclohexane, a typical volatile organic compound (VOC), poses high risks to the environment and humans. Herein, synthesized PdAg/Fe₂O₃ catalysts exhibited exceptional catalytic performance for cyclohexane combustion at lower temperatures (50% mineralization temperature (T₅₀) of 199 °C, 90% mineralization temperature (T₉₀) of 315 °C) than Pd/Fe₂O₃ (T₅₀ of 262 °C, T₉₀ of 335 °C) and Fe₂O₃ (T₅₀ of 305 °C, T₉₀ of 360 °C). In addition, PdAg/Fe₂O₃ displayed enhanced stability by alloying Ag with Pd. The redox and acidity of the PdAg/Fe₂O₃ were studied by XPS, H₂-TPR, and NH₃-TPD. In situ diffuse reflectance infrared Fourier transform spectroscopy and proton-transfer-reaction time-of-flight mass spectrometry were applied to identify the intermediates formed on the catalyst surface and in the tail gas during oxidation, respectively. Results suggested that loading PdAg onto Fe₂O₃ significantly enhanced the adsorption and activation of oxygen and cyclohexane, oxidative dehydrogenation of cyclohexane to benzene, and catalytic cracking of cyclohexane to olefins at low temperatures. This in-depth study will benefit the design and application of efficient catalysts for the effective combustion of VOCs at low temperatures.