镍
氢键
聚合物
共轭体系
电化学
氧化还原
材料科学
金属有机骨架
金属
扩散
氢气储存
无机化学
化学工程
化学
氢
电极
高分子化学
有机化学
分子
物理化学
复合材料
冶金
吸附
工程类
物理
热力学
作者
Liubin Wang,Youxuan Ni,Xuesen Hou,Li Chen,Fujun Li,Jun Chen
标识
DOI:10.1002/anie.202008726
摘要
Abstract Organic electrode materials suffer from low electronic conductivity and poor structure stability. Herein, a metal–organic polymer, Ni‐coordinated tetramino‐benzoquinone (Ni‐TABQ), is synthesized via d–π hybridization. The polymer chains are stitched by hydrogen bonds to feature as a robust two‐dimensional (2D) layered structure. It offers both electron conduction and Na + diffusion pathways along the directions of the polymer chains and the hydrogen bonds. With both the conjugated benzoid carbonyls and imines as the redox centers for the insertion and extraction of Na + , the Ni‐TABQ delivers high capacities of about 469.5 mAh g −1 at 100 mA g −1 and 345.4 mAh g −1 at 8 A g −1 . The large capacities are sustained for 100 cycles with almost 100 % coulombic efficiencies. The exceptional electrochemical performance is attributed to the unique 2D electron conduction and Na + diffusion pathways enabled by the robust Ni–N and hydrogen bonds.
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