Predicting Nitrogen‐Based Families of Compounds: Transition‐Metal Guanidinates TCN3 (T=V, Nb, Ta) and Ortho‐Nitrido Carbonates T′2CN4 (T′=Ti, Zr, Hf)

Due to its unsurpassed capability to engage in various sp hybridizations or orbital mixings, carbon may contribute in expanding solid-state nitrogen chemistry by allowing for different complex anions, such as the known NCN