催化作用
化学
钯
劈理(地质)
分子
化学选择性
异构化
光化学
纳米孔
有机化学
材料科学
断裂(地质)
复合材料
作者
Yonglai Lu,Yoshinori Yamamoto,Abdulrahman I. Almansour,Natarajan Arumugam,Ming Bao
出处
期刊:Chinese Journal of Catalysis
[China Science Publishing & Media Ltd.]
日期:2018-11-01
卷期号:39 (11): 1746-1752
被引量:10
标识
DOI:10.1016/s1872-2067(18)63151-1
摘要
An efficient and highly chemoselective heterogeneous catalyst system for quinoline hydrogenation was developed using unsupported nanoporous palladium (PdNPore). The PdNPore-catalyzed chemoselective hydrogenation of quinoline proceeded smoothly under mild reaction conditions (low H2 pressure and temperature) to yield 1,2,3,4-tetrahydroquinolines (py-THQs) in satisfactory to excellent yields. Various synthetically useful functional groups, such as halogen, hydroxyl, formyl, ethoxycarbonyl, and aminocarbonyl groups, remained intact during the quinoline hydrogenation. No palladium was leached from PdNPore during the hydrogenation reaction. Moreover, the catalyst was easily recovered and reused without any loss of catalytic activity. The results of kinetic, deuterium-hydrogen exchange, and deuterium-labeling experiments indicated that the present hydrogenation involves heterolytic H2 splitting on the surface of the catalyst.
科研通智能强力驱动
Strongly Powered by AbleSci AI