铀酰
化学
配体(生物化学)
表面改性
惰性
组合化学
离子
配位复合体
路易斯酸
离子交换
无机化学
有机化学
物理化学
催化作用
金属
受体
生物化学
作者
Skye Fortier,Trevor W. Hayton
标识
DOI:10.1016/j.ccr.2009.06.003
摘要
Uranyl (UO22+) is an exceptionally stable molecular species, characterized by a linear OUO geometry and short U–O bonds. Its two oxo ligands are thought to be inert to exchange and resistant to functionalization. However, a growing body of literature suggests that this assessment may need to be reevaluated. This review summarizes the chemistry of the two oxo ligands of the uranyl ion. In particular, we explore the interaction of the uranyl oxo ligands with Lewis acids, and outline attempts to selectively functionalize the oxo ligands of uranyl by chemical means. We also discuss the kinetic and mechanistic knowledge for oxo ligand exchange under acidic, basic and photolytic conditions.
科研通智能强力驱动
Strongly Powered by AbleSci AI