摘要
Advanced Energy MaterialsVolume 5, Issue 4 1401408 Communication Solid Electrolyte: the Key for High-Voltage Lithium Batteries Juchuan Li, Corresponding Author Juchuan Li Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USAE-mail: [email protected], [email protected]Search for more papers by this authorCheng Ma, Cheng Ma Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USASearch for more papers by this authorMiaofang Chi, Miaofang Chi Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USASearch for more papers by this authorChengdu Liang, Chengdu Liang Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USASearch for more papers by this authorNancy J. Dudney, Corresponding Author Nancy J. Dudney Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USAE-mail: [email protected], [email protected]Search for more papers by this author Juchuan Li, Corresponding Author Juchuan Li Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USAE-mail: [email protected], [email protected]Search for more papers by this authorCheng Ma, Cheng Ma Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USASearch for more papers by this authorMiaofang Chi, Miaofang Chi Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USASearch for more papers by this authorChengdu Liang, Chengdu Liang Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USASearch for more papers by this authorNancy J. Dudney, Corresponding Author Nancy J. Dudney Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831 USAE-mail: [email protected], [email protected]Search for more papers by this author First published: 14 October 2014 https://doi.org/10.1002/aenm.201401408Citations: 507Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract A solid-state high-voltage (5 V) lithium battery is demonstrated to deliver a cycle life of 10 000 with 90% capacity retention. The solid electrolyte enables the use of high-voltage cathodes and Li anodes with minimum side reactions, leading to a high Coulombic efficiency of 99.98+%. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description aenm201401408-sup-0001-S1.pdf335.8 KB Supplementary Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1a) A. Kraytsberg, Y. Ein-Eli, Adv. Energy Mater. 2012, 2, 922; b) C.-X. Zu, H. Li, Energy Environ. Sci. 2011, 4, 2614; c) B. C. Melot, J.-M. Tarascon, Acc. Chem. Res. 2013, 46, 1226. 2M. Hu, X. Pang, Z. Zhou, J. Power Sources 2013, 237, 229. 3a) D. Liu, W. Zhu, J. Trottier, C. Gagnon, F. Barray, A. Guerfi, A. Mauger, H. Groult, C. Julien, J. Goodenough, RSC Adv. 2014, 4, 154; b) Q. M. Zhong, A. Bonakdarpour, M. J. Zhang, Y. Gao, J. R. Dahn, J. Electrochem. Soc. 1997, 144, 205; c) C. Sigala, A. Verbaere, J. L. Mansot, D. Guyomard, Y. Piffard, M. Tournoux, J. Solid State Chem. 1997, 132, 372; d) H. Shigemura, M. Tabuchi, H. Kobayashi, H. Sakaebe, A. Hirano, H. Kageyama, J. Mater. Chem. 2002, 12, 1882. 4R. Verrelli, J. Hassoun, A. Farkas, T. Jacob, B. Scrosati, J. Mater. Chem. A 2013, 1, 15329. 5N. P. Pieczonka, L. Yang, M. P. Balogh, B. R. Powell, K. Chemelewski, A. Manthiram, S. A. Krachkovskiy, G. R. Goward, M. Liu, J.-H. Kim, J. Phys. Chem. C 2013, 117, 22603. 6a) S. Li, C. Chen, J. Camardese, J. Dahn, J. Electrochem. Soc. 2013, 160, A1517; b) X. Wu, S. Wang, X. Lin, G. Zhong, Z. Gong, Y. Yang, J. Mater. Chem. A 2014, 2, 1006. 7S. Brutti, G. Greco, P. Reale, S. Panero, Electrochim. Acta 2013, 106, 483. 8a) J. Arrebola, A. Caballero, J. Gómez-Cámer, L. Hernán, J. Morales, L. Sánchez, Electrochem. Commun. 2009, 11, 1061; b) H. Xiang, X. Zhang, Q. Jin, C. Zhang, C. Chen, X. Ge, J. Power Sources 2008, 183, 355; c) B. Guo, X. Yu, X.-G. Sun, M. Chi, Z.-A. Qiao, J. Liu, Y.-S. Hu, X.-Q. Yang, J. B. Goodenough, S. Dai, Energy Environ. Sci. 2014; c)d) S. Tan, Y. J. Ji, Z. R. Zhang, Y. Yang, ChemPhysChem 2014, 15, 1956. 9N. P. Pieczonka, Z. Liu, P. Lu, K. L. Olson, J. Moote, B. R. Powell, J.-H. Kim, J. Phys. Chem. C 2013, 117, 15947. 10Y. K. Sun, Y. S. Lee, M. Yoshio, K. Amine, Electrochem. Solid State Lett. 2002, 5, A99. 11M. Armand, J. M. Tarascon, Nature 2008, 451, 652. 12a) L. Hu, Z. Zhang, K. Amine, Electrochem. Commun. 2013, 35, 76; b) Z. Zhang, L. Hu, H. Wu, W. Weng, M. Koh, P. C. Redfern, L. A. Curtiss, K. Amine, Energy Environ. Sci. 2013, 6, 1806. 13F. Ding, W. Xu, G. L. Graff, J. Zhang, M. L. Sushko, X. Chen, Y. Shao, M. H. Engelhard, Z. Nie, J. Xiao, J. Am. Chem. Soc. 2013, 135, 4450. 14a) J. Liu, A. Manthiram, Chem. Mater. 2009, 21, 1695; b) D. Liu, J. Trottier, P. Charest, J. Fréchette, A. Guerfi, A. Mauger, C. Julien, K. Zaghib, J. Power Sources 2012, 204, 127; c) J. Li, L. Baggetto, S. K. Martha, G. M. Veith, J. Nanda, C. Liang, N. J. Dudney, Adv. Energy Mater. 2013, 3, 1275; d) S.-X. Zhao, X.-F. Fan, Y.-F. Deng, C.-W. Nan, Electrochim. Acta 2012, 65, 7; e) K. Yang, L. Z. Fan, J. Guo, X. H. Qu, Electrochim. Acta 2012, 63, 363. 15N. Kamaya, K. Homma, Y. Yamakawa, M. Hirayama, R. Kanno, M. Yonemura, T. Kamiyama, Y. Kato, S. Hama, K. Kawamoto, Nat. Mater. 2011, 10, 682. 16Z. Liu, W. Fu, E. A. Payzant, X. Yu, Z. Wu, N. J. Dudney, J. Kiggans, K. Hong, A. J. Rondinone, C. Liang, J. Am. Chem. Soc. 2013, 135, 975. 17G. Sahu, Z. Lin, J. Li, Z. Liu, N. Dudney, C. Liang, Energy Environ. Sci. 2014, 7, 1053. 18E. Rangasamy, G. Sahu, J. Keum, A. Rondinone, N. Dudney, C. Liang, J. Mater. Chem. A 2014, 2, 4111. 19N. J. Dudney, Mater. Sci. Eng.: B 2005, 116, 245. 20a) X. Yu, J. Bates, G. Jellison, F. Hart, J. Electrochem. Soc. 1997, 144, 524; b) E. Herbert, W. E. Tenhaeff, N. J. Dudney, G. Pharr, Thin Solid Films 2011, 520, 413; c) J. J. Xu, D. Xu, Z. L. Wang, H. G. Wang, L. L. Zhang, X. B. Zhang, Angew. Chem. Int. Ed. 2013, 52, 3887. 21K. Takada, Acta Mater. 2013, 61, 759. 22A. Patil, V. Patil, D. Wook Shin, J.-W. Choi, D.-S. Paik, S.-J. Yoon, Mater. Res. Bull. 2008, 43, 1913. 23T. Uemura, K. Goto, M. Ogawa, K. Harada, J. Power Sources 2013, 240, 510. 24K. Takada, N. Ohta, L. Zhang, K. Fukuda, I. Sakaguchi, R. Ma, M. Osada, T. Sasaki, Solid State Ionics 2008, 179, 1333. 25A. Brazier, L. Dupont, L. Dantras-Laffont, N. Kuwata, J. Kawamura, J.-M. Tarascon, Chem. Mater. 2008, 20, 2352. 26K. Takahashi, K. Hattori, T. Yamazaki, K. Takada, M. Matsuo, S. Orimo, H. Maekawa, H. Takamura, J. Power Sources 2013, 226, 61. 27J. H. Woo, J. E. Trevey, A. S. Cavanagh, Y. S. Choi, S. C. Kim, S. M. George, K. H. Oh, S.-H. Lee, J. Electrochem. Soc. 2012, 159, A1120. 28a) K. M. Shaju, P. G. Bruce, Dalton Trans. 2008, 5471; b) S. H. Choi, Y. J. Hong, Y. C. Kang, Nanoscale 2013, 5, 7867; c) J. Xiao, X. L. Chen, P. V. Sushko, M. L. Sushko, L. Kovarik, J. J. Feng, Z. Q. Deng, J. M. Zheng, G. L. Graff, Z. M. Nie, D. W. Choi, J. Liu, J. G. Zhang, M. S. Whittingham, Adv. Mater. 2012, 24, 2109; d) J. H. Kim, N. P. Pieczonka, L. Yang, ChemPhysChem 2014, 15, 1940. 29a) B. Wang, J. Bates, F. Hart, B. Sales, R. Zuhr, J. Robertson, J. Electrochem. Soc. 1996, 143, 3203; b) B. Fleutot, B. Pecquenard, H. Martinez, M. Letellier, A. Levasseur, Solid State Ionics 2011, 186, 29; c) Y. Hamon, A. Douard, F. Sabary, C. Marcel, P. Vinatier, B. Pecquenard, A. Levasseur, Solid State Ionics 2006, 177, 257. 30C. Yada, A. Ohmori, K. Ide, H. Yamasaki, T. Kato, T. Saito, F. Sagane, Y. Iriyama, Adv. Energy Mater. 2014, 4, 1301416. 31L. Yang, B. Ravdel, B. L. Lucht, Electrochem. Solid State Lett. 2010, 13, A95. 32Y. Kim, N. J. Dudney, M. Chi, S. K. Martha, J. Nanda, G. M. Veith, C. Liang, J. Electrochem. Soc. 2013, 160, A3113. 33C. M. Lopez, J. T. Vaughey, D. W. Dees, J. Electrochem. Soc. 2009, 156, A726. 34a) B. Neudecker, N. Dudney, J. Bates, J. Electrochem. Soc. 2000, 147, 517; b) N. Kuwata, J. Kawamura, K. Toribami, T. Hattori, N. Sata, Electrochem. Commun. 2004, 6, 417. 35N. Sata, K. Eberman, K. Eberl, J. Maier, Nature 2000, 408, 946. 36G. Delaizir, V. Viallet, A. Aboulaich, R. Bouchet, L. Tortet, V. Seznec, M. Morcrette, J. M. Tarascon, P. Rozier, M. Dollé, Adv. Funct. Mater. 2012, 22, 2140. 37a) K. Kanamura, R. Oosone, H. Munakata, M. Kotobuki, Ceramic Engineering and Science Proceedings, (Ed: Y. Katoh, K. M. Fox, H.-T. Lin, I. Belharouak, S. Widjaja, D. Singh), American Ceramic Society, Inc., Westerville OH 2011; b) T. A. Yersak, H. A. Macpherson, S. C. Kim, V. D. Le, C. S. Kang, S. B. Son, Y. H. Kim, J. E. Trevey, K. H. Oh, C. Stoldt, Adv. Energy Mater. 2013, 3, 120; c) S. Ito, S. Fujiki, T. Yamada, Y. Aihara, Y. Park, T. Y. Kim, S.-W. Baek, J.-M. Lee, S. Doo, N. Machida, J. Power Sources 2014, 248, 943. Citing Literature Volume5, Issue4February 18, 20151401408 ReferencesRelatedInformation