二硒化钨
钼
钨
材料科学
二硒醚
半导体
过渡金属
范德瓦尔斯力
卤素
纳米技术
结晶学
催化作用
化学
光电子学
分子
冶金
有机化学
烷基
硒
作者
S. Mary Delphine,M. Jayachandran,C. Sanjeeviraja
标识
DOI:10.1080/0889311x.2011.611130
摘要
Molybdenum/tungsten dichalcogenides constitute a well-defined family of compounds which crystallize in a layer-type structure. These compounds have properties tailored for use as storage electrodes in rechargeable photoelectrochemical solar energy storage cells. These compounds find a wide range of applications in the field of catalysis and as lubricants at high temperatures and pressures. Among IV–VI semiconducting compounds, (Mo/W)Se2-layered compound dichalcogenides exhibit a hexagonal structure. The basic structural unit of such a compound is a sandwich of three planes: one plane of transition metal atoms between two halogen atoms. These sandwich-type structures are only loosely bound together through weak Van der Waals forces, and therefore, extremely anisotropic physical properties result. The material properties of the layered semiconductors, molybdenum diselenide (MoSe2), tungsten diselenide (WSe2) and molybdenum tungsten diselenide (Mo x W1 − x Se2), are prepared by different methods and presented in this review.
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