Geochemical characteristics and resource potential of shale gas in Sichuan Basin, China

Shale gas is a green, low-carbon and clean unconventional natural gas energy. China is rich in shale gas resources. Accelerating shale gas exploration and development is of great practical significance to improve China's energy structure and achieve the goal of "2030 carbon peak and 2060 carbon neutralization". The Ordovician Wufeng Formation to Silurian Longmaxi Formation in Sichuan Basin is the key strata for shale gas exploration and development in China. Based on the experimental analysis of shale gas in Wufeng Formation to Longmaxi Formation in Weiyuan, Changning, Zhaotong, Fuling and Weirong areas of Sichuan Basin, this paper systematically analyzes the geochemical characteristics of shale gas in Wufeng Formation to Longmaxi Formation, discusses the genesis of shale gas, the causes of hydrocarbon isotope inversion and the source of shale gas, and looks forward to the exploration prospects of shale gas resources in the basin. It has important guiding significances for shale gas exploration and development in Sichuan Basin and even in China. The results show that: (1) The shale gas of Wufeng-Longmaxi Formations is a typical dry gas, and the hydrocarbon isotopes are distributed in negative sequence. The carbon isotopes of alkane gas in Changning, Zhaotong and Fuling areas are heavier and have a higher degree of thermal evolution than those in Weiyuan and Weirong areas, and the rare gas is of crustal origin. (2) Shale gas of Wufeng-Longmaxi Formations is a thermogenic oil-typed gas at high-over mature stage, which is mainly the mixture of crude oil cracking gas and kerogen cracking gas. The hydrocarbon isotope inversion of alkane gas is mainly caused by the mixing of crude oil cracking gas and kerogen cracking gas at high-over mature stage, the exchange between formation water and methane at high evolution stage and so on. (3) The carbon isotopic values of methane in shale gas of Wufeng-Longmaxi Formations match the carbon isotopic values of kerogen in mudstones of Longmaxi Formation of Lower Silurian, which conforms to the law of carbon isotopic fractionation δ13Ckerogen>δ13Coil>δ13Calkane gas. (4) The total amount of marine, marine continental transitional and continental facies shale gas resources in Sichuan Basin is about 41.5 × 1012 m3, with broad exploration prospects in resource potential.