Screw extrusion pretreatment for high-yield lignocellulose nanofibrils (LCNF) production from wood biomass and non-wood biomass

To develop a facile and low-cost nanofibrils process with excellent feedstock adaptability, high-yield lignocellulose nanofibrils (LCNF) are produced directly from wood and non-wood biomass using glycerol solvent via screw extrusion pretreatment. Different LCNFs are obtained from four classical raw materials (polar, pine, bamboo, and wheat straw) in this research, followed by comparing their morphological, thermochemical, and mechanical properties. More than 70 wt% of LCNF could be obtained from low-cost substrates except for LCNF from wheat straw with 62.3 wt% yield. Besides, the morphology property of wood LCNF exhibit more uniform distribution over that of non-wood LCNF due to narrower size distribution. Strikingly, despite of the slightly lower LCNF crystallinity various from 52.4% to 62.6% obtained from four substrates, all the LCNFs separated from wood and non-wood biomass exhibit high thermal stability (Tmax over 330 °C), which is higher than conventional nanocellulose, indicating that the crystal area could be well maintained during the pretreated process. Moreover, all the LCNF films show excellent tensile strength which is close to nanocellulose materials. Besides, the Young's modulus of wood-based LCNF films is higher than that of non-wood based LCNF films. Overall, LCNF with excellent performance could be achieved from low-cost biomass by our facile process, which provides a feasible route for industrial production of bio-based nanofilms.