材料科学
光电流
分解水
能量转换效率
光电子学
氮化镓
异质结
半导体
纳米颗粒
载流子
纳米技术
光催化
化学
生物化学
图层(电子)
催化作用
作者
Ameer Abdullah,Muhammad Ali Johar,Aadil Waseem,Indrajit V. Bagal,Mostafa Afifi Hassan,June Key Lee,Sang‐Wan Ryu
标识
DOI:10.1016/j.mseb.2021.115514
摘要
Photoelectrochemical (PEC) water splitting is a reliable method for converting abundant solar energy into chemical energy. Thus far, the reported efficiencies for the energy conversion of solar to hydrogen (STH) do not meet the criterion for commercial use. A significant improvement in efficiency could be achieved by designing heterostructures, changing the size and shape of gold nanoparticles (Au NPs) and improving the crystal quality of materials used for PEC water splitting. In this study, we synthesized a noble metal/semiconductor composite photoanode by depositing Au NPs on gallium nitride (GaN). Under unbiased conditions, the Au NP/GaN composite photoanode exhibited an 11.4% enhancement in photocurrent density compared to pristine GaN. In addition, the STH conversion efficiency was increased to 1.14% and the incident photon-to-current conversion efficiency reached 67%. These achieved improvements are attributed to efficient light harvesting, effective Au NP/GaN interface for the extraction of hot electrons from Au NPs, and efficient charge-carrier-collection efficiency of the GaN photoelectrode.
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