阳极
阴极
之字形的
压力降
甲醇燃料
功率密度
直接甲醇燃料电池
材料科学
电流密度
甲醇
化学
分析化学(期刊)
化学工程
机械
功率(物理)
热力学
几何学
色谱法
电极
工程类
物理
有机化学
量子力学
物理化学
数学
作者
Jegathishkumar Ramasamy,P. Karthikeyan,Thanarajan Kumaresan,Mathan Chandran,Rui Chen
标识
DOI:10.1016/j.ijhydene.2021.10.033
摘要
The existing flow channels like parallel and gird channels have been modified for better fuel distribution in order to boost the performance of direct methanol fuel cell. The main objective of the work is to achieve minimized pressure drop in the flow channel, uniform distribution of methanol, reduced water accumulation, and better oxygen supply. A 3D mathematical model with serpentine channel is simulated for the cell temperature of 80 °C, 0.5 M methanol concentration. The study resulted in 40 mW/cm2 of power density and 190 mA/cm2 of current density at the operating voltage of 0.25 V. Further, the numerical study is carried out for modified flow channels to discuss their merits and demerits on anode and cathode side. The anode serpentine channel is unmatched by the modified zigzag and pin channels by ensuring the better methanol distribution under the ribs and increased the fuel consumption. But the cathode serpentine channel is lacking in water management. The modified channels at anode offered reduced pressure drop, still uniform reactant distribution is found impossible. The modified channels at cathode outperform the serpentine channel by reducing the effect of water accumulation, and uniform oxygen supply. So the serpentine channel is retained for methanol supply, and modified channel is chosen for cathode reactant supply. In comparison to cell with only serpentine channel, the serpentine anode channel combined with cathode zigzag and pin channel enhanced power density by 17.8% and 10.2% respectively. The results revealed that the zigzag and pin channel are very effective in mitigating water accumulation and ensuring better oxygen supply at the cathode.
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