有机粘土
材料科学
纳米复合材料
聚合物
己二酸
多孔性
高分子
化学工程
复合材料
高分子化学
化学
生物化学
工程类
作者
Roberto Scaffaro,Roberto Scaffaro,Michele Gammino,Francesco Paolo La Mantia
标识
DOI:10.1016/j.polymdegradstab.2021.109549
摘要
In this work, we report the effect of an organoclay on the photochemical weathering of nanocomposites based on a poly(butylene adipate-co-terephthalate) (PBAT)/poly(lactic acid) (PLA) blend. The evolution of physicochemical properties was monitored by integrating spectroscopic, mechanical, and morphological analyses. A robust relationship was found between the molecular transformations of the polymer macromolecules and the morpho-mechanical properties of irradiated films. Moreover, the analysis of insoluble fractions extracted from nanocomposites pointed out that free-standing, porous structures, displaying an unprecedented thickness as great as 100 µm, were formed, thus unambiguously demonstrating that the organoclay increased the propagation depth of photochemical crosslinking reactions by 10 times with respect to previously reported results on PBAT. The pore architecture and chemical structure of such crosslinked networks proved to change depending on organoclay content of films.
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