物理吸附
催化作用
共沉淀
傅里叶变换红外光谱
漫反射红外傅里叶变换
泊洛沙姆
化学工程
X射线光电子能谱
介孔材料
材料科学
选择性催化还原
色散(光学)
无机化学
化学
核化学
光催化
有机化学
共聚物
聚合物
复合材料
工程类
物理
光学
作者
Changsheng Liu,Xiaojin Han,Yaqin Hou,Yaoping Guo,Yong-Jin Liu,N. Xiang,Yan Cui,Zhanggen Huang
出处
期刊:Chinese Journal of Catalysis
[China Science Publishing & Media Ltd.]
日期:2017-11-01
卷期号:38 (11): 1831-1841
被引量:16
标识
DOI:10.1016/s1872-2067(17)62897-3
摘要
An Fe/TiO2 catalyst with uniform mesopores was synthesized using Pluronic F127 as a structure-directing agent. This catalyst was used for selective catalytic reduction of NO with NH3. The catalytic activity and resistance to H2O and SO2 of Fe/TiO2 prepared by a template method were better than those of catalysts synthesized using impregnation and coprecipitation. The samples were characterized using N2-physisorption, transmission electron microscopy, ultraviolet-visible spectroscopy, X-ray photoelectron spectroscopy, and in situ diffuse reflectance infrared Fourier-transform spectroscopy. The results showed that Pluronic F127 acted as a structural and chemical promoter; it not only promoted the formation of a uniform mesoporous structure, leading to a higher surface area, but also improved dispersion of the active phase. In addition, the larger number of Lewis acidic sites, indicated by the presence of coordinated NH3 species (1188 cm−1) and the N–H stretching modes of coordinated NH3 (3242 and 3388 cm−1), were beneficial to mid-temperature selective catalytic reduction reactions.
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