纳米传感器
荧光
检出限
水溶液中的金属离子
选择性
化学
离子
量子产额
分析化学(期刊)
材料科学
猝灭(荧光)
光化学
核化学
纳米技术
色谱法
有机化学
催化作用
量子力学
物理
作者
Xin Zhang,Lizhu Fu,Yujiao Hou,Nan Long,Guangqiang Zhu,Xiaofang Liao,Lidong Zhou,Jinghua Lu,Weijun Kong
标识
DOI:10.1016/j.indcrop.2021.114439
摘要
Trace detection of Fe3+ ions in complex matrices requires the development of highly sensitive sensors. Nitrogen-doped carbon dots (N-CDs) with admirable fluorescence efficiency, high photostability, and good biocompatibility have drawn special interest in fluorescent sensing of metal ions. In this work, a facile and economical microwave-assisted strategy was introduced for rapid synthesis of green fluorescence N-CDs, which were comprehensively characterized to display excitation-dependent fluorescent behavior with a high quantum yield of 18.1%, as well as good water solubility and high selectivity to Fe3+ ions. Then, a N-CDs based fluorescent “on-off” nanosensor was successfully fabricated for sensitive assay of Fe3+ ions. In the presence of Fe3+ ions, fluorescence of N-CDs was remarkably quenched due to the formation of N-CDs/Fe3+ complex through static quenching mechanism. Under the optimized synthetic and sensing conditions, the newly-developed nanosensor was free from other interfering metal ions for selective detection Fe3+ ions ranging from 1.0 to 80.0 μM with a low limit of detection of 1.0 μM, which are comparable with other methods. Practical application in Dioscorea opposita Thunb. samples exhibited fascinating recoveries of 98.5%−109.2% with relative standard deviations lower than 4.7%. The N-CDs based fluorescent nanosensor with simple construction, high selectivity and extremely sensitivity contributed a promising tool for rapid and environmental-friendly assay of Fe3+ions in a large number of actual samples.
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