Advanced oxidation processes for the elimination of microplastics from aqueous systems: Assessment of efficiency, perspectives and limitations

Microplastics act as a vector of heavy metals, organic pollutants, pathogens and resistance genes in the environment further aggravate the pollution of plastics. The conventional wastewater/water treatment processes can physically capture and remove most of microplastics, but the success rates varies. How to quickly remove a large amount of microplastics from aqueous system is a key research topic at present. Recently, advanced oxidation processes (AOPs) as a green elimination strategy has attracted attention because of its effective elimination, strong destruction and safety. The molecular chain of microplastics can be gradually degraded into small molecular organics until H2O and CO2 by strong oxidizing free radical produced by AOPs. Unfortunately, problematically, the elimination of microplastics in aqueous system by AOPs is recently carried out on a laboratory scale. The application and implementation of this strategy are restricted by long reaction time, low liquid phase degradation efficiency and the formation of nanoplastics. Generally, the technology is still in its infancy, and most studies are carried out under laboratory conditions. The degradation of microplastics in aqueous system also needs appropriate conditions, but it is not always feasible under field conditions in AOPs. Although AOPs can be used as a green degradation technology to eliminate microplastics in aqueous systems in theory, it still needs to be furtherly explored in practical application. Consequently, before AOPs as a green elimination strategy is successfully applied to the effective remove microplastics, more in-depth research is still required, such as the setting from single condition to complex environment, the transfer from laboratory scale to field scale, and systematic toxicity evaluation of corresponding products.