电镀(地质)
化学
电解质
硼氢化
钒酸盐
无机化学
电导率
钙
拉曼光谱
分析化学(期刊)
物理化学
电极
生物化学
有机化学
催化作用
地球物理学
地质学
物理
光学
作者
Aaron M. Melemed,Dhyllan A. Skiba,Betar M. Gallant
标识
DOI:10.1021/acs.jpcc.1c09400
摘要
Learning how to tailor Ca2+ speciation and electroactivity is of central importance to engineer next-generation battery electrolytes. Using an exemplar dual-salt electrolyte, Ca(BH4)2 + Ca(TFSI)2 in THF, this work examines how to modulate a critical parameter proposed to govern electroactivity, the BH4-/Ca2+ ratio. Introduction of a more-dissociating source of Ca2+ via Ca(TFSI)2 drives re-speciation of strongly ion-paired Ca(BH4)2, confirmed by ionic conductivity, Raman spectroscopy, and reaction microcalorimetry measurements, generating larger populations of charged species and enhancing plating currents. Ca plating is possible when [Ca(TFSI)2] < [Ca(BH4)2] and thus BH4-/Ca2+ >1, but a dramatic shut-down of plating activity occurs when [Ca(TFSI)2] > [Ca(BH4)2] (BH4-/Ca2+ <1), directly evidencing the significance of coordination-shell chemistry on plating activity. Ca(BH4)2 + TBABH4 in THF, which enables enrichment of BH4- concentrations compared to Ca2+, is also examined; ionic conductivity and plating currents also increase compared to Ca(BH4)2/THF, with the latter related in part to a decrease in solution resistance. These findings delineate future directions to modulate Ca2+ coordination towards achieving both high plating activity and reversibility.
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