堆积
化学
猝灭(荧光)
斯托克斯位移
光化学
溶剂变色
烷氧基
单晶
溶剂
烷基
荧光
吡咯
结晶学
有机化学
量子力学
物理
作者
Wenjing Liu,Yongtao Wang,Guixian Ge,Lei Ma,Litong Ren,Yan Zhang
标识
DOI:10.1016/j.dyepig.2019.107704
摘要
It is a hot topic to furnish aggregation-caused quenching luminogens with aggregation-induced emission (AIE) active units and explore their optical properties and inherent mechanism. In this paper, two newly designed and synthesized difluoroboron β-diketonate complexes (TPE-BF2-2AP and TPE-BF2-2MP) with tetra (phenyl) ethylene (TPE) and N-alkyl pyrrole unit exhibit solvatochromism, AIE and mechanochromic properties. Although the alkyl substituents with slight difference, TPE-BF2-2AP relative to TPE-BF2-2MP show distinct increased stokes shift and red shifted fluorescence emission in organic solvents. More interestingly, single crystal analysis reveals that TPE-BF2-2MP forms head-to-head anti-parallel stacking, while TPE-BF2-2AP adopts a scarce head-to-head cross non-parallel stacking, leading to enhanced quantum efficiency from 0.24 to 0.34 before/after grinding, and blue shifted fluorescence emission compared with TPE-BF2-2MP in aggregated states and crystalline states. In addition, the two luminogens exhibit multi-state emission properties by grinding, solvent fumigation and heating due to incomplete transformation between amorphous and crystalline state.
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