化学
羰基化
锰
催化作用
戒指(化学)
键裂
劈理(地质)
组合化学
有机化学
高分子化学
一氧化碳
断裂(地质)
工程类
岩土工程
作者
Tim Meyer,Zhu Yin,Xiao‐Feng Wu
标识
DOI:10.1016/j.tetlet.2019.02.028
摘要
Abstract Herein, we report a manganese-catalyzed ring-opening carbonylation of cyclobutanol derivatives through cyclic C C bond cleavage. The reaction happens via a radical-mediated pathway to selectively generate 1,5-ketoesters. A variety of substrates with substituents on the aromatic ring reacted with linear alcohols of different chain lengths. Obtained aliphatic esters are very attractive since they are usually difficult to access.
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