钝化
钙钛矿(结构)
卤化物
开路电压
材料科学
带隙
载流子寿命
光电子学
溴化物
能量转换效率
电压
钙钛矿太阳能电池
化学工程
无机化学
化学
纳米技术
图层(电子)
硅
电气工程
工程类
作者
Xiaohui Yi,Yichen Mao,Lu Zhang,Jing Zhuang,Yanyan Zhang,Ningli Chen,Tao Lin,Yuanzhi Wei,Fuyi Wang,Jizheng Wang,Cheng Li
标识
DOI:10.1002/smtd.202000441
摘要
Suppressing non-radiative recombination via passivating surface defects of perovskite films has demonstrated an excellent strategy for high-performance perovskite solar cells (PSCs). However, it is still hard to realize both high open-circuit voltage (Voc ) of >1.2 V and high power conversion efficiency (PCE) of >22%, because the optimized bandgap of perovskite films is less than 1.60 eV for efficient light harvesting and Voc deficit is generally unavoidable due to carriers recombination. Here, the surface of the perovskite film is treated with a series of phenylhydroxylammonium halide salts and it is found that all of them can remarkably prolong the carrier lifetime owing to their excellent capability of surface defects passivation. The best PSC with phenylbutylammonium bromide treatment realizes a PCE of 22.67% with a Voc of 1.216 V, corresponding to a small Voc deficit of ≈344 mV.
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