材料科学
电化学
阳极
储能
锂(药物)
纳米技术
重量分析
电池(电)
锂离子电池的纳米结构
电化学储能
电极
超级电容器
功率(物理)
物理化学
有机化学
内分泌学
化学
物理
医学
量子力学
作者
Shan Fang,Dominic Bresser,Stefano Passerini
标识
DOI:10.1002/aenm.201902485
摘要
Abstract Lithium‐ion batteries (LIBs) with outstanding energy and power density have been extensively investigated in recent years, rendering them the most suitable energy storage technology for application in emerging markets such as electric vehicles and stationary storage. More recently, sodium, one of the most abundant elements on earth, exhibiting similar physicochemical properties as lithium, has been gaining increasing attention for the development of sodium‐ion batteries (SIBs) in order to address the concern about Li availability and cost—especially with regard to stationary applications for which size and volume of the battery are of less importance. Compared with traditional intercalation reactions, conversion reaction‐based transition metal oxides (TMOs) are prospective anode materials for rechargeable batteries thanks to their low cost and high gravimetric specific capacities. In this review, the recent progress and remaining challenges of conversion reactions for LIBs and SIBs are discussed, covering an overview about the different synthesis methods, morphological characteristics, as well as their electrochemical performance. Potential future research directions and a perspective toward the practical application of TMOs for electrochemical energy storage are also provided.
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