插层(化学)
相间
电解质
石墨
石墨烯
阳极
溶剂化
化学物理
化学
剥离(纤维)
离子
材料科学
无机化学
电极
化学工程
纳米技术
物理化学
有机化学
复合材料
工程类
生物
遗传学
作者
Kang Xu,Arthur v. Cresce,Unchul Lee
出处
期刊:Langmuir
[American Chemical Society]
日期:2010-05-06
卷期号:26 (13): 11538-11543
被引量:489
摘要
Efforts were made to differentiate the contributions to the so-called "ion transfer" barrier at the electrolyte/graphite junction from two distinct processes: (1) desolvation of Li+ before it enters graphene interlayer and (2) the subsequent migration of bare Li+ through the ad hoc interphase. By leveraging a scenario where no substantial interphase was formed on Li+ intercalation hosts, we were able to quantify the distribution of "ion transfer" activation energy between these two interfacial processes and hence identify the desolvation process of Li+ as the major energy-consuming step. The result confirmed the earlier belief that the rate-determining step in the charging of a graphitic anode in Li+ intercalation chemistry relates to the stripping of solvation sheath of Li+, which is closely interwoven with the interphasial resistance to Li+ migration.
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