芳基
区域选择性
锗
锗化合物
化学
药物化学
催化作用
有机化学
硅
烷基
作者
Yani Luo,Leiyang Lv,Zhiping Li
出处
期刊:Chemcatchem
[Wiley]
日期:2023-05-19
卷期号:15 (13)
被引量:2
标识
DOI:10.1002/cctc.202300467
摘要
Abstract The light‐promoted regioselective germylation of aryl propiolamides/alkynoates with germanium hydrides is reported. The germyl‐containing spiro[4.5]trienones were obtained when N ‐arylpropiolamides were used via sequential C−Ge and C−C bond formation, while aryl alkynoates delivered the vinylgermanes with radical Smiles rearrangement and CO 2 release.
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