位阻效应
化学
反应性(心理学)
空间因子
计算化学
立体化学
组合化学
医学
替代医学
病理
作者
Lars Killian,Roel L. M. Bienenmann,Daniël L. J. Broere
出处
期刊:Organometallics
[American Chemical Society]
日期:2022-12-02
卷期号:42 (1): 27-37
被引量:4
标识
DOI:10.1021/acs.organomet.2c00458
摘要
Steric properties of ligands are an important parameter for tuning the reactivity of the corresponding complexes. For various ligands used in mononuclear complexes, methods have been developed to quantify their steric bulk. In this work, we present an expansion of the buried volume and the G-parameter to quantify the steric properties of 1,8-napthyridine-based dinuclear complexes. Using this methodology, we explored the tunability of the steric properties associated with these ligands and complexes.
科研通智能强力驱动
Strongly Powered by AbleSci AI