正交晶系
薄膜
三元运算
材料科学
分析化学(期刊)
太阳能电池
晶格常数
沉积(地质)
光电子学
衍射
纳米技术
结晶学
化学
物理
晶体结构
光学
古生物学
生物
色谱法
程序设计语言
计算机科学
沉积物
作者
Raju Nandi,Pravin S. Pawar,Rahul Kumar Yadav,Neerugatti KrishnaRao Eswar,Indu Sharma,Yong Tae Kim,Jaeyeong Heo
标识
DOI:10.1021/acsaem.2c02887
摘要
Binary tin chalcogenides (SnS and SnSe) are investigated extensively for thin-film solar cells (TFSCs). The conventional sulfo-selenization of elemental Sn follows multiple and rigorous procedures. Herein, we have developed a one-step procedure for developing a mixed-phase SnSxSe1–x thin film. Meanwhile, reports on synthesizing mixed-phase SnSxSe1–x (0 < x < 1) thin films for TFSCs are scarce. In this study, SnSxSe1–x thin films are synthesized by vapor transport deposition using a mixture of SnS and SnSe source powders for evaporation. Energy-dispersive X-ray spectroscopy analysis confirmed the formation of homogeneous and uniformly distributed ternary SnSxSe1–x alloys. The corresponding X-ray diffraction patterns revealed that the 2θ values of the characteristic (111) peak of the orthorhombic structure shifted toward a lower angle as the Se-content increased owing to the expansion of the lattice constant. The S-rich SnSxSe1–x devices exhibited a superior Voc, while the Se-rich devices displayed a superior Jsc. The highest efficiency of 3.75% was achieved for the optimized SnS0.70Se0.30 absorber layer, which is significantly higher than those of pure SnS or SnSe devices.
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