硝基苯
化学
催化作用
选择性
检出限
荧光
粉末衍射
热稳定性
金属有机骨架
猝灭(荧光)
光化学
无机化学
物理化学
有机化学
结晶学
色谱法
物理
量子力学
吸附
作者
Shuangshuang Chen,Leilei Li,Shuang Liu,Shuyuan Liu,Wenzhen Wang,Xiao‐Jun Xu
标识
DOI:10.1016/j.molstruc.2024.137504
摘要
The employment of metal-organic frameworks (MOFs) as fluorescence sensors for the detection of environmental pollutants and/or heterogeneous catalysts for CO2 conversion is of great importance for protecting human health. For this purpose, we synthesized a new Eu-MOF [Eu2(btpdc)2·(HCOO)2]n (1) (H2btpdc = benzo[b]thiophene-2,5-dicarboxylic acid) with its three-dimensional structure characterized by single-crystal X-ray diffraction. The powder X-ray diffraction (PXRD) and thermal gravimetric analysis (TGA) results indicate that 1 has high chemical durability, good water stability and high thermal stability. Fluorescence sensing investigations demonstrate that 1 is a smart chemical sensor towards nitrobenzene (NB) detection with high sensitivity, high selectivity and good regeneration performance. A high quenching constant (Ksv = 2.33 × 105 M−1) and a low detection limit (LOD = 0.038 μM) are obtained. Combined with experiments and density functional theory calculations, the mechanism of fluorescence quenching of 1 by NB was also revealed. Furthermore, 1 can serve as a smart catalyst for the cycloaddition reaction of CO2 with epoxides to synthesize cyclic carbonates, displaying high activity, high selectivity, and good generality.
科研通智能强力驱动
Strongly Powered by AbleSci AI