炔烃
醛
卡宾
电化学
化学
碘
有机化学
组合化学
催化作用
电极
物理化学
作者
Haitao Tang,Kai-Wei Chen,Guodong Wang,Fei‐Hu Cui,Shuhui Li,Ying-Ming Pan
标识
DOI:10.1002/cctc.202401418
摘要
A new type of alkyne esterification was developed under electrochemical conditions using alkyne aldehydes and alcohol compounds as starting materials and carbene and iodine as mediators. Through this method, external oxidants and transition metals are excluded and the alkyne bond is fully preserved. This approach is compatible with a wide range of substrates and various functional groups and provides a green and mild new route for directly converting alkyne aldehydes into alkyne esters.
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