Rational Design of Highly Porous Donor–Acceptor Based Conjugated Microporous Polymer for Photocatalytic Benzylamine Coupling Reaction

Abstract Conjugated microporous polymers (CMPs) are an important class of organic materials with several useful features like, inherent nanoscale porosity, large specific surface area and semiconducting properties, which are very demanding for various sustainable applications. Carbazole building blocks are extensively used in designing photocatalysts due to easy electron donation and hole transportation. In the current study, a new CMP material CBZ‐CMP containing carbazole unit used for photocatalytic C═N coupling reaction under blue light irradiation is designed. The CBZ‐CMP framework is made through the polycondensation of 4,4′‐di(9H‐carbazol‐9‐yl)‐1,1′‐biphenyl using FeCl 3 as a catalyst. The CBZ‐CMP shows very high BET surface area of 1536 m 2 g −1 together with unimodal porosity (ca. 1.7 nm supermicropore), nanowire‐like particle morphology (16–18 nm diameter), and low band gap property. The bi‐phenyl moiety functions as the electron accepting center and the carbazole unit acts as the donor center, which accounts for the low band gap energy of CBZ‐CMP. This nanoporous semiconducting CBZ‐CMP material for photocatalytic benzylamine coupling reaction is explored, where it shows good conversion together with high selectivity under mild reaction conditions. This study offers simple method of preparation of a D–A–D‐based porous photocatalyst for sustainable synthesis of value‐added organics.