Innovative two-dimensional porphyrin-integrated metal-organic frameworks for enhanced photocatalytic hydrogen peroxide generation in pure water

• The novel 2D-MOFs, specifically Ce-TCPP and La-TCPP, with a consistent topological framework, were successfully synthesized. • The architecture of 2D-MOFs fine-tunes the electron and hole transport pathways, thus enhancing the photocatalytic activity . • La-TCPP exhibited significant photocatalytic performance, achieving an H 2 O 2 yield of 79.75 μmol/g/h in pure water. In the quest for eco-friendly and efficient synthesis of hydrogen peroxide (H 2 O 2 ), a chemical with extensive applications, photocatalytic production emerges as a promising clean technique. Metal-organic frameworks (MOFs), known for their exceptional porosity and geometric customizability, stand at the forefront of potential photocatalytic materials. Yet, the conventional three-dimensional topologies of MOFs pose a challenge, impeding the swift transit of photogenerated electrons and thereby curbing performance enhancements. In this vein, we have engineered novel 2D porphyrin-based MOFs , specifically Ce-TCPP and La-TCPP, utilizing diverse metal sources while maintaining a consistent topological framework. This design strategy streamlines the electron and hole transport pathways, thus elevating the photocatalytic activity . Delving into the structural nuances of these MOFs , our research unveiled that the photocatalytic activity experienced a marked shift upon altering the metal cluster types. Notably, La-TCPP, as an efficacious catalyst, demonstrated an H 2 O 2 yield of 79.75 μmol/g/h in pure water, sans any sacrificial agents. Rigorous testing confirmed the robust stability of both MOFs . This study marks the inaugural design and synthesis of a single crystal structure of La-TCPP. By strategically varying metal cluster compositions, we have fine-tuned the architecture of two-dimensional MOFs. This approach sheds light on the intricate structure-activity relationship governing the photocatalytic synthesis of H 2 O 2 , paving the way for future advancements in the field.