Corresponding author at: Surface reactivity versus microcracks in Ni-rich layered oxide cathodes: Which is critical for long cycle life？

Capacity fading of Ni-rich cathode is thought to originate from the formation of inactive rock-salt phase induced by surface reactivity and the isolation of active material caused by microcracks due to anisotropic volume contraction of grains. It is generally assumed that inhibiting the formation of microcracks within secondary particle by radially aligned microstructure is a vital aspect for suppressing capacity fading. However, the new researches about reduction of microcracks simply by certain electrolytes call a question on the origin of microcracks and the critical factor for the cycle life of cathodes. Herein, LiNi0.92Co0.04Mn0.04O2 cathodes with different surface characteristic and radially aligned microstructure were synthesized by doping with high valence elements using some hydroxide precursor. The effects of W6+ and/or Mo6+ induced surface phase and microstructure on electrochemical performance were investigated. Despite the inferior radially aligned, size-refined primary grains and higher degree of microcracks, W6+ doped cathode still possesses alleviated parasitic reactions, higher crystal structural stability and capacity retention than Mo6+ doped materials, because of the enhanced cathode-electrolyte interfacial stability. The results contend that the consequence of surface reactivity on determining cycle life of Ni-rich cathodes is more critical than that of microcracks, and efforts relating to constructing intact and uniform stable surface phase will exhibit greater potential to promote the performance of Ni-rich cathodes than microstructural refinement.