博罗
材料科学
兴奋剂
钠
硼
化学
冶金
光电子学
有机化学
作者
Ahmad Marzuki,Hery Purwanto,Artono Dwijo Sutomo,Harjana Harjana,Ari Handono Ramelan,Devara Ega Fausta,Retno Willy Astuti,Anisa Nandita Rahmawati,Frisca Aulia Alvyanti,Rivina Oktafiani
出处
期刊:Materials Science Forum
日期:2024-03-22
卷期号:1118: 3-10
摘要
Five boro-tellurite glasses with chemical formula 55TeO 2 -(12-x)B 2 O 3 -32ZnO-(1+x)Na 2 O (TZBN), (x= 0; 1; 2; 3; 4; mole%) were successfully synthesized by conventional melt-quenching technique. The physical properties of the glass was studied to understand effect of partial substitution between B 2 O 3 and Na 2 O. The density was measured using pycnometer based on Archimedes law. The other physical properties can be obtained by assisted some mathematical equation. Refer to the measurement, the density was found decreased by 4.905 to 4.590 gr/cm 3 because the molecular weight difference between B 2 O 3 and Na 2 O. Meanwhile the molar volume increased by 25.05 to 27.11 cm 3 /mole due to higher atomic radii of Na rather than B which raise NBO inside the glass network. Meanwhile, OPD , V o , polaron radius, inter-ionic distance, packing density,and number of bond per unit volume consequently have been decreased. While the Field strength has increase due to stronger Na-O bonds. Reflects from the results the TZBN glasses could be used as active material for laser.
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