Improved Performance in Li–S Batteries Due to In Situ CuS Formation from Cu Nanowires

Lithium–sulfur batteries offer theoretical capacities of 800–1600 mAh g–1 of active material and are therefore one of the most promising new battery chemistries currently under intensive study. However, the low electronic conductivity of the sulfur and the discharge products imposes energy penalties during the discharge and charge steps. In addition, the reduction of sulfur during discharge forms soluble polysulfides, which will diffuse to, and react with, the lithium metal anode. To address these two challenges, copper nanowires were introduced into the composite cathode to improve the electronic conductivity of the cathode and to provide electrostatic anchoring points for the formed polysulfide anions. The addition of the conductive copper nanowires resulted in the in situ formation of copper sulfide, which was shown to decrease the resistivity of the SEI layer on the anode, as manifested by diminished lithium plating and stripping overpotentials. Higher copper loadings exacerbated the dissolution of the copper sulfide during deep discharge and increased the concentration of displaced capping ligands in the electrolyte. Both phenomena generate species that react at the lithium anode, resulting in a more resistive SEI layer.