This study explores the modification of pore structures in porous silica materials synthesized using sodium silicate and waste gelatin, under varying silica-to-gelatin ratios. At ratios of 1.0-1.5, bimodal porous silica with mesopores and macropores emerged due to spaces between silica nanoparticles and clusters, following gelatin elimination. The study further evaluated the obtained bimodal porous silica as polyethyleneimine (PEI) supports for CO