In‐situ Polymerized Single Lithium‐ion Conducting Binder as an Integrated Strategy for High Voltage LNMO Electrodes

Batteries & SupercapsEarly View e202300383 Research Article In-situ Polymerized Single Lithium-ion Conducting Binder as an Integrated Strategy for High Voltage LNMO Electrodes Jorge Olmedo-González, Jorge Olmedo-González orcid.org/0000-0001-6832-9345 Instituto Politécnico Nacional, Escuela Superior de Ingeniería Química e Industrias Extractivas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorDr. Gregorio Guzmán-González, Dr. Gregorio Guzmán-González orcid.org/0000-0002-8080-0862 Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this authorDr. Arturo Manzo-Robledo, Dr. Arturo Manzo-Robledo orcid.org/0000-0002-8570-4028 Instituto Politécnico Nacional, Escuela Superior de Ingeniería Química e Industrias Extractivas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorDr. Daniel Ramírez-Rosales, Dr. Daniel Ramírez-Rosales Instituto Politécnico Nacional, Escuela Superior de Física y Matemáticas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorStephany N. Arellano-Ahumada, Stephany N. Arellano-Ahumada Instituto Politécnico Nacional, Escuela Superior de Física y Matemáticas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorMarco A. Vera-Ramírez, Marco A. Vera-Ramírez Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this authorDr. Ignacio González, Dr. Ignacio González orcid.org/0000-0002-9651-2515 Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this authorDr. Rosa de Guadalupe González-Huerta, Dr. Rosa de Guadalupe González-Huerta orcid.org/0000-0002-6016-4723 Instituto Politécnico Nacional, Escuela Superior de Ingeniería Química e Industrias Extractivas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorDr. Guadalupe Ramos-Sanchez, Corresponding Author Dr. Guadalupe Ramos-Sanchez [email protected] orcid.org/0000-0002-3976-4724 Departamento de Ingeniería de Procesos e Hidráulica, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this author Jorge Olmedo-González, Jorge Olmedo-González orcid.org/0000-0001-6832-9345 Instituto Politécnico Nacional, Escuela Superior de Ingeniería Química e Industrias Extractivas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorDr. Gregorio Guzmán-González, Dr. Gregorio Guzmán-González orcid.org/0000-0002-8080-0862 Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this authorDr. Arturo Manzo-Robledo, Dr. Arturo Manzo-Robledo orcid.org/0000-0002-8570-4028 Instituto Politécnico Nacional, Escuela Superior de Ingeniería Química e Industrias Extractivas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorDr. Daniel Ramírez-Rosales, Dr. Daniel Ramírez-Rosales Instituto Politécnico Nacional, Escuela Superior de Física y Matemáticas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorStephany N. Arellano-Ahumada, Stephany N. Arellano-Ahumada Instituto Politécnico Nacional, Escuela Superior de Física y Matemáticas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorMarco A. Vera-Ramírez, Marco A. Vera-Ramírez Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this authorDr. Ignacio González, Dr. Ignacio González orcid.org/0000-0002-9651-2515 Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this authorDr. Rosa de Guadalupe González-Huerta, Dr. Rosa de Guadalupe González-Huerta orcid.org/0000-0002-6016-4723 Instituto Politécnico Nacional, Escuela Superior de Ingeniería Química e Industrias Extractivas, UPALM, 07738 Mexico City, MéxicoSearch for more papers by this authorDr. Guadalupe Ramos-Sanchez, Corresponding Author Dr. Guadalupe Ramos-Sanchez [email protected] orcid.org/0000-0002-3976-4724 Departamento de Ingeniería de Procesos e Hidráulica, Universidad Autónoma Metropolitana-Iztapalapa, Av. San Rafael Atlixco 186, 09340 Mexico City, MéxicoSearch for more papers by this author First published: 17 November 2023 https://doi.org/10.1002/batt.202300383Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract High voltage LNMO electrodes: The utilization of a boron-based single lithium-conducting polymer as a binder in high-voltage LiNi0.5Mn1.5O4 cathodes results in a substantial 38 % increase in capacity at 1 C discharge and effectively decreases polarization by concentration. This strategy also mitigates reactivity and Mn2+ disproportionation issues, thereby enhancing electrochemical stability. These advancements position the in-situ polymerization of this binder as a viable option for widespread commercial applications. Abstract High voltage spinel LiNi0.5 Mn1.5O4 (LNMO) is a promising material for next generation lithium-Ion batteries. However, its reactivity near 5 V possess stability and cycling challenges. In this study, a novel integrated approach is employed using a single lithium-ion conducting polymer binder (SLICPB) to prevent interactions with reactive anions and create a protective layer against electrolyte decomposition. The proposed SLICPB in-situ polymerization in the LNMO electrodes simplifies the preparation process, reducing costs. SLICPB properties effectively decrease polarization by concentration. For instance, at a discharge capacity of 68 mAh g−1, the voltage hysteresis difference is 0.31 V, enabling higher capacity at 1 C (a 38 % increase) compared to traditional binder electrodes. Notably, this integrated strategy completely replaces the traditional binder without any need for additives, thus avoiding any extra weight in the electrode preparation. Furthermore, SLICPB properties successfully decreasereactivity and diminish the leaching of Mn2+, as evaluated through differential electrochemical mass spectrometry and electron paramagnetic resonance, respectively. Conflict of interest The authors declare no conflict of interest. Open Research Data Availability Statement The data that support the findings of this study are available from the corresponding author upon reasonable request. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description batt202300383-sup-0001-misc_information.pdf666.9 KB Supporting Information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1M. Erakca, M. Baumann, W. Bauer, L. de Biasi, J. Hofmann, B. Bold, M. Weil, iScience 2021, 24, 102437. 10.1016/j.isci.2021.102437 CASPubMedGoogle Scholar 2D. L. Wood, J. Li, S. J. An, Joule 2019, 3, 2884–2888. 10.1016/j.joule.2019.11.002 Web of Science®Google Scholar 3K. I. Ozoemena, M. Kebede, in Nanostructure Sci. Technol. Nanomater. Adv. Batter. Supercapacitors (Eds.: K. I.. Ozoemena, S. 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