Volatile fingerprints of different parts of Chongming saffron (Crocus sativus) flowers by headspace‐gas chromatography‐ion mobility spectrometry and in vitro bioactive properties of the saffron tepals

Abstract In this work, the volatile fingerprints of different parts of Chongming saffron flowers (stigmas, stamens, and tepals) were analyzed and compared for the first time by headspace‐gas chromatography‐ion mobility spectrometry. Three different parts of saffron flowers could be clearly distinguished using principal component analysis based on signal intensity data of gas chromatography‐ion mobility spectrometry. Therefore, gas chromatography‐ion mobility spectrometry coupled with principal component analysis method could be employed as a new method for authentication and quality control of saffron for the reason of frequent addition with stamens and/or tepals as adulterants in saffron. Moreover, the bioactive composition (total flavonoids, total phenolics, and total anthocyanins) and bioactive properties of saffron tepals were evaluated. The results indicated that aqueous, ethanol, and ethyl acetate extracts of saffron tepals exhibited good radical scavenging (2,2‐Diphenyl‐1‐picrylhydrazyl, ABTS, and OH) and enzyme (α‐amylase/α‐glucosidase) inhibition activities, which probably were attributed to the bioactive components contained in the extracts. This approach would provide the important information for monitoring the quality of saffron as well as exploring the utilization of saffron tepals in functional food technology. Practical Application This study demonstrated that the HS‐GC‐IMS method might be used as a new strategy for quality control of saffron, and the saffron tepals were rich source of bioactive components that could be used in health‐promoting products.