吸附
碳纤维
氢氧化物
环境修复
X射线光电子能谱
多孔性
金属
材料科学
化学
无机化学
核化学
化学工程
冶金
有机化学
复合数
污染
复合材料
工程类
生物
生态学
作者
Minwang Laipan,Haoyang Fu,Runliang Zhu,Luyi Sun,Jianxi Zhu,Hongping He
标识
DOI:10.1038/s41598-017-07775-8
摘要
Abstract Recycling solid waste as functional materials is important for both environmental remediation and resource recycling. This study attempts to recycle spent Cu/Fe layered double hydroxide (Cu/Fe-LDH) which is generated from the adsorption of dyes by converting to Cr(VI) reductant and porous carbon material. Results showed that the obtained reductant was mainly composed of Fe 0 and Cu 0 , and exhibited good reductive activity toward Cr(VI). The species of Fe 0 , Fe 2+ , Cu 0 , and Cu + all favored the reduction of Cr(VI) according to X-ray photoelectron spectroscopy analysis. During Cr(VI) removal, solution pH could increase to neutral which caused the metal ions to precipitate near completion. On the other hand, the spent Cu/Fe-LDH could be employed to produce porous carbon materials, and the generated waste metals solution herein could be reused for LDH synthesis. Specific surface areas of the obtained carbon materials varied from 141.3–744.2 m 2 /g with changes in adsorbed amount of dyes on the LDH. This study illustrates that all the components of wastes can be useful resources, offering a simple recycling approach for similar organic-inorganic solid wastes. This work also enlightens us that designing a proper initial product is crucial to make waste recycling simpler.
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