萘普生
吸附
人工湿地
生物降解
化学
污染物
环境化学
双酚A
降级(电信)
污水处理
悬浮物
环境工程
废水
色谱法
环境科学
有机化学
医学
电信
替代医学
病理
吸附
计算机科学
环氧树脂
作者
Cristina Ávila,Anna Pedescoll,Víctor Matamoros,Josep M. Bayona,Joan Garcı́a
出处
期刊:Chemosphere
[Elsevier]
日期:2010-09-23
卷期号:81 (9): 1137-1142
被引量:125
标识
DOI:10.1016/j.chemosphere.2010.08.006
摘要
A continuous injection experiment was implemented in a pilot-scale horizontal subsurface flow constructed wetland system to evaluate the behavior of four pharmaceuticals and personal care products (i.e. ibuprofen, naproxen, diclofenac and tonalide) and a phenolic estrogenic compound (i.e. bisphenol A). The treatment system consisted of an anaerobic reactor as a primary treatment, followed by two 0.65 m2 wetlands (B1 and B2) working in parallel and connected to a 1.65 m2 wetland (B3) operating in series. Overall removal efficiencies for the selected compounds ranged from 97% to 99%. The response curves of the injected pollutants show that the behavior of these compounds strongly depends on their sorption and biodegradation characteristics. While about 50% of ibuprofen was removed in B1 and B2, 99% was achieved at B3, where the dissolved oxygen concentration was significantly higher (B1–B2 = 0.5 mg L−1 and B3 = 5.4 mg L−1). Naproxen and diclofenac were efficiently removed (93%) in B1 and B2, revealing anaerobic degradation as a probable removal mechanism. Moreover, tonalide and bisphenol A were readily removed in the small wetlands (94% and 83%, respectively), where the removal of total suspended solids was 93%. Therefore, given their high hydrophobicity, sorption onto the particulate matter stands for the major removal mechanism. However, the tentative identification of carboxy-bisphenol A as an intermediate degradation product in B3 suggested biodegradation as a relevant bisphenol A removal pathway under aerobic prevailing conditions.
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