化学
硼氢化
氢原子
对映选择合成
马尔科夫尼科夫法则
激进的
立体选择性
环氧化物
电子转移
组合化学
立体化学
催化作用
有机化学
区域选择性
烷基
作者
Juan M. Cuerva,Araceli G. Campaña,José Justicia,Antonio Rosales,Juan L. Oller‐López,Rafael Robles,Diego J. Cárdenas,Elena Buñuel,J. Enrique Oltra
标识
DOI:10.1002/anie.200600831
摘要
Hydrogen-atom transfer from water to free radicals can be mediated by aqua complexes of titanium(III) (see scheme). Asymmetric epoxidation in combination with [Cp2TiCl]/H2O-mediated reductive epoxide opening can be viewed as an alternative with complementary stereoselectivity to the hydroboration–epoxidation method for the enantioselective synthesis of anti-Markovnikov alcohols from alkenes. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z600831_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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