阳极
锂(药物)
离子
硅
碳纤维
材料科学
氟
壳体(结构)
化学工程
纳米技术
化学
电极
复合材料
光电子学
有机化学
复合数
冶金
物理化学
医学
工程类
内分泌学
作者
Chengxin Liu,Zeping Wang,Qian Wang,Jinbo Bai,Hui Wang,Xiaojie Liu
标识
DOI:10.1016/j.jcis.2024.04.208
摘要
Silicon is considered as the next-generation anode material for lithium-ion batteries due to its high theoretical specific capacity and abundant crustal abundance. However, its poor electrical conductivity results in slow diffusion of lithium ions during battery operation. Simultaneously, the alloying process of silicon undergoes a 300 % volume change, leading to structural fractures in silicon during the cycling process. As a result, it loses contact with the current collector, continuously exposing active sites, and forming a sustained solid electrolyte interface (SEI) membrane.This paper presents the design of a fluorine-ion-regulated yolk–shell carbon-silicon anode material, highlighting the following advantages: (a) Alleviating volume changes through the design of a yolk–shell structure, thereby maintaining material structural integrity during cycling. (b) Carbon shell prevents silicon from coming into contact with the electrolyte, simultaneously improving silicon's electrical conductivity and increasing ion/electron conductivity. (c) Utilizing fluorine-ion interface modification to obtain an SEI membrane rich in fluorine components (such as LiF), thereby enhancing its long cycling performance. The F-Si@Void@C exhibits outstanding electrochemical performance, with a reversible capacity of 1166 mAh/g after 900 cycles at a current density of 0.5 A/g.
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