Preparation and photoluminescence study of rare-earth-free red emitting La3Ga5SiO14:Mn4+phosphors

Given the growing interest in eco-friendly lighting solutions, the use of high-quality phosphors has become integral to the advancement of all-solid white light-emitting diodes (WLEDs). One novel phosphor, La 3 Ga 5 SiO[Formula: see text]:Mn[Formula: see text] (LGS), has been successfully synthesized via a high-temperature solid-state reaction. The crystal structure of LGS is classified as belonging to the trigonal phase, with a space group P321. The excitation spectrum exhibits a wide peak within the wavelength range of 280–440 nm. It emits a highly intense red light, with a peak emission occurring at 715 nm within the spectral range of 670–740 nm is attributed to the transition of Mn[Formula: see text] from 4 A 2g to 4 T 2g . LGS:Mn[Formula: see text] demonstrates a favorable quantum efficiency of 16% when doped with a concentration of 0.25 mol% Mn. The decay curve of LGS:Mn[Formula: see text] exhibits a pattern of decreasing lifetime as the dopant concentration increases. Additionally, the LGS:Mn[Formula: see text] products demonstrate a CIE chromaticity of (0.688, 0.2644), which is located within the deep red light region. All the aforementioned findings support the potential application of LGS:Mn[Formula: see text] specimens in WLEDs, thereby contributing to the progress of environmentally friendly and energy-efficient lighting.